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A student aims to deposit a thin metallic film on $\mathrm{SiO}_{2}$ substrate, with an adhesion layer between the metal film and substrate, in a contiguous planar fashion. Island type of growth must be avoided. The student performs an extensive optimization exercise. Which one of the following steps is in the right direction?

  1. Choose a metallic adhesion layer with very low interfacial energy with the deposited thin film.
  2. Choose a metallic adhesion layer with very low interfacial energy with $\mathrm{SiO}_{2}$, irrespective of its interaction with metal film to be deposited
  3. Increase the substrate temperature and decrease the deposition rate
  4. Use intermittent stages of deposition followed by annealing

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