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Consider a real gas, which obeys the following equation-of-state:

$$v=\dfrac{R T}{P}+C_{1}-\dfrac{C_{2}}{P v},$$

where $v$ is the mass specific volume, $P$ is the pressure, $T$ is the temperature and $R$ is the gas constant. $C_{1}$ and $C_{2}$ are constants. If $s$ is the mass specific entropy, the quantity $\left(\dfrac{\partial s}{\partial v}\right)_{T}$ for the gas is given by

  1. $\dfrac{R}{v}$
  2. $\dfrac{R^{2} T}{P v^{2}}$
  3. $\dfrac{R}{v-C_{1}}$
  4. $\dfrac{C_{1} C_{2}}{T v}$

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