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In thermogravimetric analysis (TGA), weight change of a material sample during decomposition with temperature is shown in the figure below.


$\mathrm{W}_{\mathrm{i}}$ and $\mathrm{W}_{\mathrm{f}}$ represent the weight of the material, corresponding to temperatures $T_{i}$ and $T_{f}$, respectively. Which of the following factor(s) can influence $T_{i}$ and $T_{f}$ ?

  1. Heating rate
  2. Particle size of the material
  3. Atmosphere in the sample chamber
  4. Initial weight of the sample

     

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