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​For $\mathrm{Al}-4.5 \mathrm{wt} \% \mathrm{Cu}$ alloy, the correct sequence of precipitation during age hardening at room temperature is

  1. GP zone $\rightarrow \theta^{\prime \prime} \rightarrow \theta^{\prime} \rightarrow \theta$
  2. GP zone $\rightarrow \theta^{\prime} \rightarrow \theta^{\prime \prime} \rightarrow \theta$
  3. GP zone $\rightarrow \theta^{\prime \prime} \rightarrow \theta \rightarrow \theta^{\prime}$
  4. GP zone $\rightarrow \theta \rightarrow \theta^{\prime} \rightarrow \theta^{\prime \prime}$

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